Increasing inhibition efficiency and studying technological properties of environmentally safe corrosion inhibitor for protecting oilfield equipment in mineralised aquatic environments
UDC: 620.197.3
DOI: -
Authors:
SILIN MIKHAIL A.
1,
MAGADOVA LYUBOV A.
1,
KOTEKHOVA VIKTORIA D.
1,
KUKSINA MARINA V.1
1 National University of Oil and Gas “Gubkin University”, Moscow, Russian Federation
Keywords: corrosion inhibitor, surfactants, corrosion rate, inhibition efficiency, carbon dioxide corrosion, environmental safety, imidazoline derivatives, chemicals compatibility
Annotation:
The effectiveness of corrosion resistance determines the duration of safe and reliable use of equipment, and therefore the development and research of reagents to prevent corrosion remain in high demand. In addition to the effectiveness of the reagents used, priority attention is also paid to their environmental safety. The aim of this work is to develop and study the main characteristics of a corrosion inhibitor composition based on imidazoline derivatives for the protection of oilfield equipment in mineralized aqueous environments saturated with carbon dioxide. To increase the effectiveness of the protective effect of the inhibitor, studies were conducted on additives of surfactants and salts. It was found that surfactant additives do not enhance the protective effect of the inhibitor, and the best characteristics are achieved when adding ammonium carbonate to the composition at the concentration of 0,25 % by weight. As a result, a corrosion inhibitor is developed to protect oilfield equipment. This has high protective properties in a hydrocarbon-containing aqueous environment at an economical dosage (protective effect up to 85,9 % at an inhibitor concentration of 30 mg/l) and is characterized by compatibility with industrial demulsifiers, as well as improved environmental performance.
Bibliography:
1. GOST R 54567-2011. Neft’. Trebovaniya k himicheskim produktam, obespechivayushchie bezopasnoe primenenie ih v neftyanoj otrasli. – Vved. 2021-01-01. – M.: Standartinform, 2019. – 12 s.
2. Sriplai N., Sombatmankhong K. Corrosion inhibition by imidazoline and imidazoline derivatives: a review // Corrosion Reviews. – 2023. – No. 41 (3). – P. 237–262. – URL: http://doi.org/10.1515/corrrev-2022-0092
3. Razrabotka i issledovanie ekologicheski bezopasnogo ingibitora korrozii dlya zashchity neftepromyslovogo oborudovaniya v mineralizovannyh vodnyh sredah / M.A. Silin, L.A. Magadova, S.I. Kudryashov [i dr.] // Neftyanoe hozyajstvo. – 2024. – № 7. – S. 104–108. – DOI: 10.24887/0028-2448-2024-7-104-108
4. Izuchenie zashchitnogo dejstviya ingibitorov korrozii na osnove poverhnostno-aktivnyh ve shchestv i jodida kaliya v agressivnyh sredah / L.A. Magadova, M.A. Silin, V.D. Kotekhova [i dr.] // Trudy Rossijskogo gosudarstvennogo universiteta nefti i gaza imeni I.M. Gubkina. – 2022. – № 3 (308). – S. 139–154. – DOI: 10.33285/2073-9028-2022-3(308)-139-154
5. Synergistic effect of 2-oleyl-1-oleylamidoethyl imidazoline ammonium methylsulfate and halide ions on the inhibition of mild steel in HCl / S. Hu, A. Guo, Y. Geng [et al.] // Materials Chemistry and Physics. – 2012. – № 1. – P. 54–60.
6. ECHA CHEM database // EUROPEAN CHEMICALS AGENCY. – URL: https://echa.europa.eu/information-on-chemicals/registered-substances (data obrashcheniya: 26.02.2024).
7. GOST 9.506-87. Edinaya sistema zashchity ot korrozii i stareniya (ESZKS). Ingibitory korrozii metallov v vodno-neftyanyh sredah. Metody opredeleniya zashchitnoj sposobnosti. – Vved. 1988-07-01. – M.: Izdatel’stvo standartov, 1988. – 17 s.
8. OST 39-099-79. Ingibitory korrozii. Metod ocenki effektivnosti zashchitnogo dejstviya ingibitorov korrozii v neftepromyslovyh stochnyh vodah. – Vved. 1980-11-01. – M.: HOZU Minnefteproma, 1980. – 27 s.
9. Demulsification techniques of water-in-oil and oil-in-water emulsions in petroleum industry/ R. Zolfaghari, A. Fakhru’l-Razi, L.C. Abdullah [et al.] // Separation and Purification Technology. – 2016. – № 170. – P. 377–407. – DOI: 10.1016/j.seppur.2016.06.026
10. RD 39-030-90. Tekhnologiya kompleksnoj obrabotki neftyanyh emul’sij deemul’gatorami i ingibitorami korrozii. – Vved. 1990-10-01. – Ufa: Izdatel'stvo VNIISPTnefti, 1990. – 41 s.
11. Issledovanie ingibitorov uglekislotnoj korrozii stali dlya primeneniya v usloviyah neftegazodobychi / L.A. Magadova, K.A. Poteshkina, V.D. Vlasova [i dr.] // Tekhnologii nefti i gaza. – 2020. – № 4. – S. 14–18. – DOI: 10.32935/1815-2600-2020-129-4-14-18
12. Optimizaciya sostava ingibitora korrozii na osnove imidazolinov dlya zashchity oborudovaniya v uglekislotnoj i kislotnoj sredah / M.A. Silin, L.A. Magadova, K.A. Poteshkina [i dr.] // Himiya i tekhnologiya topliv i masel. – 2022. – № 6 (634). – S. 35–40. – DOI: 10.32935/0023-1169-2022-634-6-35-39
13. Berezhnaya A.G., Khudoleeva E.S., Chernyavina V.V. Some imidazolines and their mixtures with inorganic anions as inhibitors of acid corrosion of steel // International Journal of Corrosion and Scale Inhibition. – 2021. – Vol. 10, No. 2. – P. 649–661. – DOI: 10.17675/2305-6894-2021-10-2-11
14. Electrochemical behavior of Q235 steel in saltwater saturated with carbon dioxide based on new imidazoline derivative inhibitor / F.G. Liu, M. Du, J. Zhang, M. Qiu // Corros. Sci. – 2009. – № 51 (1). – P. 102–109. – DOI: 10.1016/j.corsci.2008.09.036
15. Microwave-assisted synthesis of organic corrosion inhibitor based imidazoline-stearic / D.U.C. Rahayu, S. Cahyani, I. Abdullah [et al.] // IOP Conference Series: Materials Science and Engineering. – 2020. – № 1. – P. 012019. – DOI: 10.1088/1757-899X/902/1/012019
16. Hydrolysis of imidazoline based corrosion inhibitor and effects on inhibition performance of X65 steel in CO2 saturated brine / A. Shamsa, E. Barmatov, T.L. Hughes [et al.] // Journal of Petroleum Science and Engineering. – 2022. – № 208. – P. 109235. – DOI: 10.1016/j.petrol.2021.109235
17. Molecular Modeling of the Inhibition Mechanism of 1-(2-Aminoethyl)-2-Alkyl-Imidazoline / J. Zhang, J. Liu, W. Yu [et al.] // Corrosion Science. – 2010. – № 6. – P. 2059–2065. – DOI: 10.1016/j.corsci.2010.02.018