Scientific and technical journal

«Oilfield engineering»

ISSN 0207-2351

Oilfield engineering
Study of the effectiveness of thermochemical removal of light organochlorine compounds from commercial oil

UDC: 665.66
DOI: 10.33285/0207-2351-2023-12(660)-59-66

Authors:

GLADUNOV OLEG V.1,
ORLOV MIKHAIL I.1,
KORYAKIN TIMOFEY YU.1,
CHERNOV ANTON E.1,
KOZLOV SERGEY A.1,
FROLOV DMITRY A.1,
KOZHIN VLADIMIR N.2,
BODOGOVSKIY SERGEY V.2,
KONOVALOV VIKTOR V.2,
NEVYADOVSKIY EVGENY YU.3

1 Samaraneftegaz, Samara, Russia
2 SamaraNIPIneft, Samara, Russia
3 NK "Rosneft", Moscow, Russia

Keywords: highly volatile organic-chlorine compounds, removal technologies, oil, thermochemical effects, destruction mechanism, process parameters

Annotation:

Currently, comprehensive measures are being taken to minimize the risks of increasing the content of light organic-chlorine compounds (LOChC) in commercial oil. The practice of field control shows that most often their increased concentration is recorded in oil after geological-technical measures and in oil-containing liquids from sludge objects (barns, additional sludge ponds, etc.). Taking into account the existing restrictions on the involvement of oil-containing liquids with a high content of chemical pollutants in the technological process, conditions are being created for the development and improvement of technologies for removing/reducing their concentration. The article presents the results of testing the thermochemical method on model mixtures and oil with a high content of LOChC. Based on the results of the studies, the efficiency of chemical pollutants removal was determined depending on the technological parameters of the process.

Bibliography:

1. Obrazovanie legkoletuchikh khlororganicheskikh soedineniy pri pervichnoy peregonke nefti v rezul’tate razlozheniya khimicheskikh reagentov, soderzhashchikh soli chetvertichnykh ammonievykh soedineniy / A.V. Sinev, T.V. Devyashin, A.M. Kunakova [i dr.] // PRONEFT’’. Professional’no o nefti. – 2019. – № 4(14). – S. 63–69.

2. Khutoryanskiy F.M. Khlororganicheskie soedineniya v nefti. Istoriya voprosa i problemy nastoyashchego // Mir nefteproduktov. Vestnik neftyanykh kompaniy. – 2002. – № 3. – S. 6–7.

3. Khlororganicheskie soedineniya v nefti: problemy i resheniya / V.V. Nosov, A.Yu. Presnyakov, A.G. Badamshin [i dr.] // Neft. khoz-vo. – 2021. – № 4. – S. 110–113. – DOI: 10.24887/0028-2448-2021-4-110-113

4. Genezis khlororganicheskikh soedineniy v nefti i nefteproduktakh (obzor) / A.G. Badamshin, V.V. Nosov, A.Yu. Presnyakov [i dr.] // Neftekhimiya. – 2021. – T. 61, № 6. – S. 776–787. – DOI: 10.31857/S0028242121060034

5. Organizatsiya kontrolya izmeneniya soderzhaniya khlororganicheskikh soedineniy na ob"ektakh podgotovki nefti AO "Samaraneftegaz" / V.N. Kozhin, V.V. Konovalov, K.L. Pashkevich [i dr.] // Neft. khoz-vo. – 2021. – № 8. – S. 102–105. – DOI: 10.24887/0028-2448-2021-8-102-105

6. Sistema kontrolya khimicheskikh reagentov, primenyaemykh v PAO "Tatneft’", na soderzhanie organicheskogo khlora / O.S. Tat’yanina, F.R. Gubaydulin, S.N. Sudykin [i dr.] // Neft. khoz-vo. – 2021. – № 7. – S. 56–58. – DOI: 10.24887/0028-2448-2021-7-56-58

7. Krikun A.N., Lestev A.E. Aktual’nye voprosy opredeleniya khlororganicheskikh soedineniy v khimreagentakh, primenyayushchikhsya v protsessakh dobychi i transportirovki nefti // Neftegazokhimiya. – 2020. – № 3-4. – S. 40–43. – DOI: 10.24412/2310-8266-2020-3-4-40-43

8. Povyshenie effektivnosti ispol’zovaniya khimicheskikh reagentov v OAO "NK "Rosneft’" / G.G. Gilaev, V.V. Gorbunov, A.M. Kuznetsov [i dr.] // Neft. khoz-vo. – 2012. – № 11. – S. 22–24.

9. Opredelenie khlororganicheskikh soedineniy v khimicheskikh reaktivakh, postavlyaemykh neftyanym kompaniyam / A.V. Frolova, A.E. Lestev, E.V. Mironova [i dr.] // Inzhenernaya praktika. – 2020. – № 4. – S. 51–54.

10. Kulonometricheskiy analiz soderzhaniya khlororganicheskikh soedineniy v promyshlenno vypuskaemykh khimicheskikh reaktivakh / A.E. Lestev, E.V. Mironova, P.A. Bogomolov [i dr.] // Vestn. tekhnologicheskogo un-ta. – 2020. – T. 23, № 11. – S. 23–27.

11. Krikun N.G. Utrachennyy kontrol’. Problemy primeneniya khimproduktov v neftyanoy otrasli Rossii // TekhNADZOR. – 2012. – № 8(69). – S. 40–41.

12. Ustanovlenie prichin obrazovaniya khlororganicheskikh soedineniy v tovarnoy nefti / C.A. Kozlov, D.A. Frolov, E.P. Kuz’mina [i dr.] // Neftepromyslovoe delo. – 2019. – № 5(605). – S. 64–69. – DOI: 10.30713/0207-2351-2019-5(605)-64-69

13. Organochlorine Compounds with a Low Boiling Point in Desalted Crude Oil: Identification and Conversion / B. Wu, Y. Li, X. Li [et al.] // Energy Fuels. – 2018. – Vol. 32, № 6. – P. 6475–6481. – URL: https://doi.org/10.1021/acs.energyfuels.8b00205

14. Priroda khlororganicheskikh soedineniy v nefti i neftyanykh fraktsiyakh / V.K. Miller, D.V. Marochkin, Yu.G. Noskov, G.A. Korneeva // Tekhnologiya nefti i gaza. – 2020. – № 6(131). – S. 3–10. – DOI: 10.32935/1815-2600-2020-131-6-3-10

15. Zhuravlev O.E., Nikol’skii V.M., Voronchikhina L.I. Thermal stability of quaternary ammonium hexafluorophosphates and halides // Russ. J. Appl. Chem. 2013. – Vol. 86, № 6. – P. 824–830. – URL: https://doi.org/10.1134/S1070427213060062

16. Issledovanie vliyaniya khimicheskikh reagentov, primenyaemykh v sisteme neftedobychi, na obrazovanie khlororganicheskikh soedineniy v nefti / O.S. Tat’yanina, F.R. Gubaydulin, S.N. Sudykin [i dr.] // Sb. nauch. tr. TatNIPIneft’. – M.: Neft. khoz-vo. – 2020. – Vyp. LXXXVIII. – S. 266–268.

17. Otsenka vliyaniya solyanoy kisloty na protsess obrazovaniya khlororganicheskikh soedineniy nefti / O.S. Tat’yanina, L.M. Abdrakhmanova, S.N. Sudykin, E.V. Zhilina // Tr. in-ta TatNIPIneft’. – 2017. – Vyp. 85. – S. 363–369.

18. Issledovanie obrazovaniya khlororganicheskikh soedineniy v rezul’tate primeneniya khimicheskikh reagentov v neftedobyche / O.S. Tat’yanina, F.R. Gubaydulin, S.N. Sudykin, E.V. Zhilina // Neft. khoz-vo. – 2022. – № 7. – S. 55–57. – DOI: 10.24887/0028-2448-2022-7-55-57

19. Osobennosti ochistki nefti ot khlororganicheskikh soedineniy / O.S. Tat’yanina, F.R. Gubaydulin, S.N. Sudykin, L.M. Abdrakhmanova // Neft. khoz-vo. – 2020. – № 8. – S. 103–105. – DOI: 10.24887/0028-2448-2020-8-103-105

20. Pat. 2221837 Ros. Federatsiya, MPK C10G 59/02. Sposob pererabotki na ustanovkakh riforminga benzinovykh fraktsiy, soderzhashchikh khlororganicheskie soedineniya / V.P. Tomin, V.A. Mikishev, A.I. Elshin [i dr.]; patentoobladatel’ OAO "Angarskaya neftekhimicheskaya kompaniya". – № 2002116460/04; zayavl. 18.06.2002; opubl. 20.01.2004, Byul. № 2.

21. Pat. 2735843 Ros. Federatsiya, MPK B01D 53/74, C01B 7/01. Sposob udaleniya khlororganicheskikh soedineniy iz nefti / M.Yu. Velichko, R.N. Khamidullin; patentoobladatel’ OOO "DISTILIUM". – № 2019133800; zayavl. 14.10.2019; opubl. 09.11.2020, Byul. № 31.

22. Pat. № 2748587 Ros. Federatsiya, MPK C10G 32/02, C10G 19/02. Sposob snizheniya soderzhaniya organicheskikh khloridov v nefti i ustanovka dlya ego osushchestvleniya / A.G. Akhmadullina, M.A. Kart, R.M. Akhmadullin [i dr.]. – № 2020114833; zayavl. 14.04.2020; opubl. 27.05.2021, Byul. № 15.

23. Pat. 2065477. Ros. Federatsiya, MPK C10G 33/02. Sposob udaleniya khlorsoderzhashchikh soedineniy iz nefti / S.Sh. Gershuni, G.A. Yushmanova, N.I. Rassokhatskiy, V.A. Chunyukin. – № 93052711/04; zayavl. 19.11.1993; opubl. 20.08.1996.

24. Pat. № 2672263 Ros. Federatsiya, MPK C10G 33/04, C10G 31/00, C10G 31/06. Sposob snizheniya soderzhaniya organicheskikh khloridov v nefti / L.M. Abdrakhmanova, O.S. Tat’yanina, S.N. Sudykin; patentoobladatel’ PAO "Tatneft’" imeni V.D. Shashina. – № 2017145787; zayavl. 25.12.2017; opubl. 13.11.2018, Byul. № 32.

25. Pat. № 2740500 Ros. Federatsiya, MPK C10G 33/02, C10G 33/04, C10G 19/00. Sposob ochistki nefti ot khlororganicheskikh soedineniy / R.R. Gimaletdinov, M.R. Usmanov, I.B. Podvintsev [i dr.]; patentoobladatel’ OOO "LUKOIL-Nizhegorodniinefteproekt". – № 2020114369; zayavl. 22.04.2020; opubl. 14.01.2021, Byul. № 2.