«Proceedings of Gubkin University»

MOLECULAR-WEIGHT DISTRIBUTION OF HYDROCARBON PRODUCTS SYNTHESIZED FROM CO AND H 2 ON COBALT CATALYSTS

UDC: 665.7
DOI: -

Authors:

¹ Gubkin Russian State University of Oil and Gas

Keywords: Fischer-Tropsch synthesis of hydrocarbons, alkanes and water production

Annotation:

The article considers molecular weight distribution of the products of synthesis of hydrocarbons from CO and H₂ as an important aspect for understanding the mechanism of the process and its implementation. It is asserted that the synthesis of hydrocarbons can be seen as reducing the polymerization of carbon monoxide with intermediate formation of oxymethylene radicals and production of alkanes and water.

Bibliography:

1. Лапидус А.Л., Крылова А.Ю.//Рос. хим. журнал. — 2000. — Т. 44. — № 1. — С. 43-49.
2. Dry M.E. Appl.Catal. A: General. — 1996. — V. 138. — 319 р.
3. Jacobs P.A., van Wouwe D.J. Mol. Catal. — 1982. — V. 17. — 145 р.
4. Dautzenberg F.M., Helle J.N., Santen R.A., Verbeek H.J. Catal. — 1977. — V. 50. — No. 1. — 8 р.
5. Satterfield C.N., Huff G.A., Longwell J.P. Ind. Eng. Chem. Proc. Des. Dev. — 1982. — V. 21. — No. 3. — 465 p.
6. Fu L., Bartholomew C.H.J. Catal. — 1985. — V. 92. — No. 1. — 376 p.
7. Madon J.R. Ibid. — 1979. — V. 57. — No. 1. — 183 p.
8. Huff G.A., Satterfield C.N.J. Catal. — 1984. — V. 85. — No. 2. — 370 p.
9. Madon J.R., Taylor W.F. Ibid. — 1981. — V. 69. — No. 1. — 32 p.
10. Satterfield C.N., Strenger H.G. Ind. Eng. Chem. Proc. Des. Dev. — 1984. — V. 23. — No. 4. — 849 p.
11. Vanhove D., Makambo P., Blanchard M.J. Chem. Soc. Chem. Communs. — 1979. — V. 14. — 605 p.
12. Henrici-Olive G., Olive S.J. Mol. Catal. — 1984. — V. 24. — No. 1. — 7 p.
13. Nijs H.H., Jacobs P.A.J. Catal. — 1980. — V. 65. — No. 2. — 328 p.
14. Mitsudo T., Boku H., Murachi S., Ishihara A., Watanabe Y. Chem. Lett. — 1985. — V. 10. — 1463 p.
15. Nijs H.H., Jacobs P.A., Vendonck J.J., Uytterhoeven J.B.J. Chem. Soc., Chem. Communs. — 1979. — 180 p.
16. Ungar R.K., Baird M. Ibid. — 1986. — 643 p.
17. McMahon K.S., Suib S.L., Johnson B.G., Bartolomew C.H.J. Catal. — 1987. — V. 106. — 47 p.
18. Ballivet-Tkachenko D., Tkachenko I.J. Mol. Catal. — 1981. — V. 13. — 1 p.
19. Tatsumi T., Shu Y.-G.l, Sugiura T., Tominaga H. Appl. Catal. — 1986. — V. 21. — 119 p.
20. Shul Y.-G., Arai. Y., Tatsumi T., Tominaga H. Bull. Chem. Soc. Japan. — 1987. — V. 60. — 2335 p.
21. Лапидус А.Л.//Изв. АН СССР. Сер. хим. — 1991. — № 12. — 2692 с.