«Proceedings of Gubkin University»

POSSIBILITY OF ULTRAHIGH RESOLUTION MASS-SPECTROMETRY APPLICATION TO ANALYZE PETROLEUM HETERO-ATOMIC COMPOUNDS

UDC: 54.07
DOI: -

Authors:

¹ Gubkin Russian State University of Oil and Gas

Keywords: ion cyclotron resonance mass spectrometry, petroleum hetero-atomic compounds, resolution, ionization techniques

Annotation:

The paper describes the possibility of ultra-high resolution ion-cyclotron resonance mass spectrometry (FT-ICR-MS) application in conjunction with the «soft» ionization techniques for molecular level characterization of petroleum hetero-atomic compounds. Two petroleum samples were analyzed and 19 clas-ses of hetero-atomic compounds with CcHhNnOoSs composition were discove-red, including carboxylic acid, pyridine bases, pyrrole-type compounds, compo-unds with one and two sulfur atoms in the molecule, as well as hybrid compound (SO, NS, O 2S 2, ONS and others). Different ionization techniques such as electrospray (ESI) and atmospheric pressure photoionization (APPI) allow us to study the composition of petroleum high molecular compounds while the high sensitivity of the method enables to simultaneously identify thousands of compounds in minimum volume of petroleum (1-2 mkl). The uniqueness of the method is the ability to analyze the heavy part of petroleum (including resin-asphaltene substances). The ultra-high resolution, sensitivity and accuracy of the method combined with simplicity of use make the method an excellent tool for petrochemical analysis.

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