«Proceedings of Gubkin University»

STUDY OF STABILIZING AND DISPERSING ABILITY OF HUMIC-CLAY COMPLEXES TOWARD OIL POLLUTION OF AQUAOUS MEDIA

UDC: 547.992.2
DOI: -

Authors:

Keywords: humic-clay complexes, humic substances, stabilizer, stabilization of emulsions of oil, natural dispersant

Annotation:

The prospects of using humic-clay complexes (HCC) as stabilizing agents for natural water-oil emulsions, the formation of which contributes to the natural process of self-purification of aqueous systems are shown. The most effective is the use of organo stabilizers with surface modified by coal humic substances. Evaluation of the effectiveness of the dispersing ability of these complexes also allows to consider the possibility of using them as natural dispersants. The use of such humic-clay complexes does not pose the risk of secondary pollution in contrast to the use of molecular surfactants.

Bibliography:

1. Мерициди И.А. Техника и технологии локализации и ликвидации разливов нефти и нефтепродуктов: Справочник/И.А. Мерициди, В.А. Ивановский, А.Н. Прохоров и др.; Под ред. И.А. Мерициди. — СПб.: НПО „Профессионал”, 2008. — 824 с.
2. Fingas M. Oil spill dispersants: a technical summary//Oil spill science and technology. — U.S.: Elsevier, 2011. — 567 р.
3. Barron M.G. Photoenhanced toxicity of aqueous phase and chemically dispersed weathered Alaska north slope crude oil to pacific herring eggs and larvae/M.G. Barron, M.G. Carls, J.W. Short, S.D. Rice//Environ. Tox. Chem. — 2003. — V. 22. — P. 650–660.
4. Kirby M.F. The toxicological impacts of oil and chemically dispersed oil: UV mediated phototoxicity and implications for environmental effects, statutory testing and response strategies/M.F. Kirby, B.P. Lyons, J. Barry, R.J. Law//Mar. Pollut. Bull. — 2007. — P. 464–488.
5. Sun J. A review of oil-suspended particulate matter aggregation — a natural process of clean-sing spilled oil in the aquatic environment/J. Sun, X. Zheng//J. Environ. Monit. — 2009. — V. 11. — P. 1801–1809.
6. Muschenheim D.K., Lee K. Removal of oil from the sea surface through particular- te interactions: review and prospectus//Spill Sci. Technol. Bull. — 2002. — V. 8. — No. 1. — P. 9–18.
7. Owens E.H., Taylor E., Humphrey B. The persistence and character of stranded oil on coarse-sediment beaches: review //Mar. Pollut. Bull. — 2008. — V. 56. — P. 14–26.
8. Owens E.H., Lee K. Interaction of oil and mineral fines on shorelines: review and assessment// Mar. Pollut. Bull. — 2003. — V. 47. — P. 397–405.
9. Vignati E., Piazza R., Lockhart T.P. Pickering emulsions: interfacial tension, colloidal layer morphology, and trapped-particle motion//Langmuir. — 2003. — V. 19. — No. 17. — P. 6650— 6656.
10. Lee K. Oil-particle interactions in aquatic environments: influence on the transport, fate, effect and remediation of oil spills//Spill Sci. Technol. Bull. — 2002. — V. 8. — No. 1. — P. 3–8.
11. Torres L.G., Iturbe R., Snowden M.J., Chowdhry B.Z., Leharne S.A. Can Pickering emulsion formation aid the removal of creosote DNAPL from porous media?//Chemosphere. — 2008. — V. 71. — Is. 1. — P. 123–132.
12. Torres L.G., Iturbe R., Snowden M.J., Chowdhry B.Z., Leharne S.A. Preparation of o/w emulsions stabilized by solid particles and their characterization by oscillatory rheology//Colloids and Surfaces A.: Physicochem. Eng. Asp. — 2007. — V. 302. — Is. 1–3. — P. 439–448.
13. Mao Z., Xu H., Wang D. Molecular mimetic self-assembly of colloidal particles//Adv. Functional Materials. — 2010. — V. 20. — Is. 7. — P. 1053–1074.
14. Lee K., Stoffyn-Egli P., Tremblay G.H., Owens E.H., Sergy G.A., Guenette C.C., Prin- ce R.C. Oil-mineral aggregate formation on oiled beaches: Natural attenuation and sediment reloca-tion//Spill Sci. Technol. Bull. — 2003. — V. 8. — No. 3. — P. 285–296.
15. Zhang H., Khatibi M., Zheng Y., Lee K., Li Z., Mullin J.V. Investigation of OMA formation and the effect of minerals//Mar. Poll. Bull. — 2010. — V. 60. — No. 11. — P. 1433–1441.
16. Khelifa A., Stoffyn-Egli P., Hill P.S., Lee K. Characteristics of oil droplets stabilized by mineral particles: the effect of oil types and temperature//Spill Sci. Technol. Bull. — 2002. — V. 8. — No. 1. — P. 19–30.
17. Venkataraman P., Jingjian T., Etham F. Attachment of a hydrophobically modified biopo-lymer at the oil-water interface in the treatment of oil spills//ACS Appl. Mater. Interfaces. — 2013. — V. 5. — P. 3572–3580.
18. Perminova I.V., Grechishcheva N.Yu., Petrosyan V.S. Relationships between structure and binding affinity of humic substances for polycyclic aromatic hydrocarbons: relevance of molecular descriptors//Environ. Sci. Technol. — 1999. — V. 33. — P. 3781–3787.
19. Орлов Д.С. Химия почв. — М.: Изд-во МГУ, 1992. — 259 с.
20. Выбор условий регистрации количественных ¹³С ЯМР-спектров гумусовых кислот/ Д.В. Ковалевский, А.Б. Пермин, И.В. Перминова, В.С. Петросян//Вестник Московского Универ-ситета. Cерия 2. Химия. — 2000. — Т 41. — № 1. — С. 39–42.
21. Использование модельных органоминеральных комплексов на основе гуминовых кис-лот и каолинита для изучения процессов сорбции ПАУ водных и почвенных сред/Н.Ю. Гречи-щева, В.А. Холодов, И.А. Вахрушкина, И.В. Перминова, С.В. Мещеряков//Защита окружающей среды в нефтегазовом комплексе. — 2012. — № 5. — С. 21–25.
22. Balcke G.U., Kulikova N.A., Hesse S., Perminova I.V., Frimmel F.H. Adsorption of humic substances onto kaolin clay related to their structural features//Soil Sci. Soc. Am. J. — 2002. — V. 66. — P. 1805–1812.
23. Kholodov V.A., Milanovskiy E.Y., Konstantinov A.I., Tyugai Z.N., Yaroslavtseva N.V., Perminova I.V. Irreversible sorption of humic substances causes a decrease in wettability of clay surfaces as measured by a sessile drop contact angle method//J. Soils and Sediments. — 2017. — DOI: 10.1007/s11368-016-1639-3.
24. Lee K., Stoffyn-Egli P., Wood P.A., Lunel T. Formation and structure of oil-mineral fines aggregates in coastal environments//Proceedings of the 21st AMOP technical seminar, Edmonton, Canada, June 10–12, 1998. — Ottawa, ON: Environment Canada, 1998. — P. 911–921.
25. Lee K., Stoffyn-Egli P. Characterization of oil-mineral aggregates//Proceedings of internatio-nal oil spill conference, Tampa, Florida, March 26-29, 2001. — Washington, DC: American Petroleum Institute, 2001. — P. 991–996.
26. Swirling flask dispersant effectiveness test, revised standard dispersant toxicity test, and bioremediation agent effectiveness//Protection of environment. The Code of Federal Regulations of the United States of America. — EPA, Washington, 2010. — T. 40, Part 300, Appendix C.