Scientific and technical journal
«Proceedings of Gubkin University»
ISSN 2073-9028
New catalyst for conversion of isobutyl alcohol into “green” hydrocarbons based on nano-sized zeolite ZSM-5
UDC: 661.183.8+661.183.1
DOI: -
Authors:
1 A.V. Topchiev Institute of Petrochemical Synthesis (TIPS RAS), Moscow, Russian Federation
2 National University of Oil and Gas “Gubkin University”, Moscow, Russian Federation
Keywords: nanosized ZSM-5 zeolite, silicon carbide, ZSM-5/SiC, hydrothermal-microwave synthesis, isobutanol
Annotation:
The article describes, for the first time, the conversion of isobutanol using catalysts synthesized by the hydrothermal-microwave method: a nanosized zeolite ZSM-5 and a material containing nanosized zeolite ZSM-5 and silicon carbide. It is shown that these catalysts enable the production of “green” fuel components and monomers from isobutanol, a product derived from renewable raw materials. The nanosized zeolite ZSM-5 demonstrates stable performance without regeneration for 20 h. Meanwhile, the material containing silicon carbide exhibits high productivity in obtaining the valuable monomer propylene, as well as greater productivity in the production of fuel components.
Bibliography:
1. Postanovlenie Pravitel’stva Rossijskoj Federacii ot 20.04.2022 № 707 (red. ot 29.10.2022) “Ob utverzhdenii Pravil predstavleniya i proverki otchetov o vybrosah parnikovyh gazov, formy otcheta o vybrosah parnikovyh gazov, Pravil sozdaniya i vedeniya reestra vybrosov parnikovyh gazov i o vnesenii izmenenij v nekotorye akty Pravitel’stva Rossijskoj Federacii”. – 2022. – URL: https://www.consultant.ru/document/cons_doc_LAW_4154272. Sheveleva N.A. Napravleniya i metody dekarbonizacii neftegazovogo sektora // Zashchita okruzhayushchej sredy v neftegazovom komplekse. – 2023 – № 2 (311). – S. 25–31. – DOI: 10.33285/2411-7013-2023-2(311)-25-31
3. Chudinov S.Yu., Mokrushin I.G., Ketov A.A. Resursosberegayushchaya tekhnologiya zameny neftyanogo syr’ya na produkt deoksigeneza rastitel’nogo masla // Zashchita okruzhayushchej sredy v neftegazovom komplekse. – 2024. – № 3 (318). – S. 58–66.
4. Isobutanol Is a Building Block for Advanced Renewable Fuels and More. – 2025. – URL: https://gevo.com/product/isobutanol (data obrashcheniya: 11.02.2025).
5. Bio-Isobutanol – Overview and Challenges. – 2018. – URL: https://stillwaterassociates.com/bio-isobutanol-overview-and-challenges/?cn-reloaded=1 (data obrashcheniya: 11.02.2025).
6. ASTM D7566-22. Standard Specification for Aviation Turbine Fuel Containing Synthesized Hydrocarbons. – 2022. – DOI: 10.1520/D7566-22
7. Experimental study of physical-chemical properties of advanced alcohol-to-jet fuels / A. Yakovlieva, S. Boichenko, V. Boshkov [et al.] // Aviation. – 2023. – Vol. 27, Issue 1. – P. 1–13. – DOI: 10.3846/aviation.2023.18564
8. Isobutanol to isobutene: Processes and catalysts / J.L. Dubois, S. Segondy, G. Postole, A. Auroux // Catalysis Today. – 2023. – Vol. 418, Issue 1. – DOI: 10.1016/j.cattod.2023.114126
9. Transformation of isobutyl alcohol to aromatics over zeolite-based catalysts / L. Yu, S. Huang, S. Zhang [et al.] // ACS Catalysis. – 2012. – Vol. 2, Issue 6. – P. 1203–1210. – DOI: 10.1021/ cs300048u
10. Conversion of isobutanol to olefins and aromatics over H-ZSM-5-based catalysts: tuning of product selectivity / Z.Y. Du, B.B. Zhang, T.S. Chen [et al.] // Energy & Fuels. – 2019. – Vol. 33, Issue 1. – P. 10176–10184. – DOI: 10.1021/acs.energyfuels.9b02454
11. Isobutanol conversion to petrochemicals using MFI-based catalysts synthesized by a hydrothermal-microwave method / A.G. Dedov, A.A. Karavaev, A.S. Loktev [et al.] // Catal. Today. – 2021. – Vol. 367. – P. 199–204. – DOI: 10.1016/j.cattod.2020.04.064
12. Pat. 2617119 Ros. Federaciya, MPK C10G3/00. Sposob polucheniya zhidkih uglevodorodov / A.G. Dedov, A.S. Loktev, I.O. Moiseev [i dr.]; patentoobladatel’ RGU nefti i gaza (NIU) imeni I.M. Gubkina. – № 2016125784; zayavl. 28.06.2016; opubl. 21.04.2017.
13. HMFI/SiC – a novel efficient catalyst for green hydrocarbon production via bioisobutanol conversion / A.G. Dedov, A.A. Karavaev, A.S. Loktev [et al.] // Mend. Comm. – 2023. – Vol. 33, Issue 6. – P. 832–835. – DOI: 10.1016/j.mencom.2023.10.031
14. Bensafi B. The universal zeolite ZSM-5: Structure and synthesis strategies. A review // Coordination Chemistry Reviews. – 2023. – Vol. 496. – DOI: 10.1016/j.ccr.2023.215397
15. Zabihpour A. Strategies to control reversible and irreversible deactivation of ZSM-5 zeolite during the conversion of methanol to propylene (MTP): A review / Chemical Engineering Science. – 2023. – Vol. 273, Issue 5. – DOI: 10.1016/j.ces.2023.118639
16. Synthesis of nanosized ZSM-5 zeolite with intracrystalline mesopores / Z. Xue, J. Ma, T. Zhang [et al.] // Materials Letters. – 2012. – Vol. 68, Issue 1. – P. 1–3. – DOI: 10.1016/ j.matlet.2011.10.019
17. A novel method for a nanosized ZSM-5 (MFI) zeolite synthesis in proton form / A.G. Dedov, A.A. Karavaev, A.S. Loktev [et al.] // Mend. Comm. – 2024. – Vol. 34, Issue 3. – P. 433–435. – DOI: 10.1016/j.mencom.2024.04.039
18. Low-temperature synthesis of three-pore system hierarchical ZSM-5 zeolite for converting palm oil to high octane green gasoline / G.T.M. Kadja, N.J. Azhari, F. Apriadi [et al.] // Microporous and Mesoporous Materials. – 2023. – Vol. 360. – DOI: 10.1016/j.micromeso.2023.112731
19. Binderless H-ZSM-5 coating on β-SiC for different alcohols dehydration / S. Ivanova, E. Vanhaecke, L. Dreibine [et al.] // Applied Catalysis A: General. – 2009. – Vol. 359, Issue 1-2. – P. 151–157. – DOI: 10.1016/j.apcata.2009.02.024
20. Pat. 2799782 Ros. Federaciya, MPK C01B 39/38. Kompozit na osnove nanorazmernogo ceolita strukturnogo tipa ZSM-5 v protonnoj forme i karbida kremniya i sposob ego polucheniya / A.G. Dedov, A.A. Karavaev, A.S. Loktev [i dr.]; patentoobladatel' Institut neftekhimicheskogo sinteza imeni A.V. Topchieva Rossijskoj akademii nauk (INHS RAN). – № 2022116387; zayavl. 17.06.2022; opubl. 11.07.2023, Byul. № 20.
21. Nano-sized H-ZSM-5 zeolite catalyzes aldol condensation reaction to prepare methyl acrylate and acrylic acid / M. Xie, Y. Ni, X. Fang [et al.] // Catal. Sci. Technol. – 2022. – Vol. 12, Issue 16. – P. 5171–5177. – DOI: 10.1039/D2CY00447J