Scientific and technical journal

«Environmental protection in oil and gas complex»

ISSN 2411-7013

Environmental protection in oil and gas complex
MECHANICAL-CHEMICAL TECHNOLOGY OF UTILIZATION OF LITHIUM-COBALT CURRENT SOURCES

UDC: 66.084.2
DOI: 10.33285/2411-7013-2021-6(303)-49-53

Authors:

RETIVOV VASILY MICHAILOVICH1,
GONOPOLSKY ADAM MICHAILOVICH2,
MAKARENKOV DMITRIY ANATOLIEVICH1,
NAZAROV VIACHESLAV IVANOVICH1,
POPOV ALEKSANDR PAVLOVICH1,
SMIRNOVA ANGELINA VITALIEVNA2

1 SIC "Kurchatov Institute" - IREA, Moscow, Russian Federation
2 National University of Oil and Gas "Gubkin University", Moscow, Russian Federation

Keywords: power sources; batteries; lithium power sources; cobalt power sources; oil and gas industry

Annotation:

Lithium and cobalt batteries are primary and secondary sources of constant readiness and are designed to provide electricity to the oil and gas industry facilities. Cobalt from spent batteries can be used for manufacturing catalysts for oil refining. Utilization of current sources is based on the method of mechanical-chemical destruction and provides a high degree of extraction of compounds from batteries. A technological scheme for recycling lithium-cobalt batteries is presented. Research has been carried out on batteries opening, breaking and grinding, followed by leaching to extract cobalt. The content of cobalt and lithium elements at each stage of battery processing is analyzed. Distilled water and citric acid were used as leaching agents. It was found that using of citric acid provides for 53,2 % of cobalt extraction from batteries.

Bibliography:

1. Pasport bezopasnosti. Oksid kobal'ta (II, III) (v sootvetstvii s Reglamentom (ES) № 1907/2006 (REACH), s popravkami, vnesennymi 453/2010/ES). – 2017. – 16 s.
2. Sergeev A.G. Vliyanie litievykh istochnikov toka na okruzhayushchuyu sredu v sravnenii s drugimi istochnikami toka // Tez. dokl. II soveshch. po litievym istochnikam toka. – Saratov, 1992. – S. 143.
3. Adaptation of minerals processing operations for lithium-ion (LiBs) and nickel metal hydride (NiMH) batteries recycling: Critical review / S. Al-Thyabat, T. Nakamura, E. Shibata, A. Iizuka // Minerals Engineering. – 2013. – Vol. 45. – P. 4–17. – DOI: 10.1016/J.MINENG.2012.12.005
4. A Method for Predetermining the Optimal Remanufacturing Point of Lithium ion Batteries / Heng Zhang, Weiwei Liu, Yazhou Dong [et al.] // Procedia CIRP. – 2014. – Vol. 15. – P. 218–222. – DOI: 10.1016/j.procir.2014.06.064
5. Gaines L., Dunn J.B. Recycling of Lithium-Ion Batteries, 2013. – 20 p. – URL: https://anl.app.box.com/s/do63o8f85iswgaqhhha7sjwfhzl94y9t
6. Shul'ga V.A. Poluchenie i obrabotka metallov i soedineniy: uchebno-metod. posobie. – M.: NIYaU MIFI, 2011. – 64 s.
7. Retsikling litiysoderzhashchikh soedineniy iz otrabotannykh istochnikov toka / A.M. Gonopol'skiy, D.A. Makarenkov, V.I. Nazarov [i dr.] // Ekologiya i prom-st' Rossii. – 2019. – T. 23, № 5. – S. 10–15. – DOI: 10.18412/1816-0395-2019-5-10-15
8. Utilizatsiya litiy-ionnykh istochnikov toka metodom mekhanokhimicheskoy destruktsii / A.M. Gonopol'skiy, D.A. Makarenkov, V.I. Nazarov, A.P. Popov // Ekologiya i prom-st' Rossii. – 2019. – T. 23, № 10. – S. 16–19. – DOI: 10.18412/1816-0395-2019-10-16-19
9. Tekhnologiya utilizatsii otrabotannykh litievykh istochnikov toka s polucheniem gidroksida i karbonata litiya na osnove mekhanoaktivirovannykh poroshkov soedineniy kobal'ta, margantsa i litiya / V.I. Nazarov, A.M. Gonopol'skiy, D.A. Makarenkov [i dr.] // Koks i khimiya. – 2020. – № 2. – S. 45–52.
10. Pat. 2082792 Ros. Federatsiya, MPK C22B 23/00. Sposob izvlecheniya kobal'ta i nikelya iz zhelezo-kobal'tovykh kekov i kontsentratov / G.L. Pashkov, V.E. Mironov, V.N. Orlov [i dr.]; patentoobladatel' In-t khimii i khimiko-metallurgicheskikh protsessov SO RAN. – № 95100996/02; zayavl. 17.01.1995; opubl. 27.06.1997.
11. Andreev O.L., Bushkova O.V., Batalov N.N. Raschet termodinamicheskikh svoystv oksidov kobal'ta (III, IV) i kobal'tita litiya // Elektrokhimicheskaya energetika. – 2006. – T. 6, № 4. – S. 187–191.
12. Gurvich L.V. Energii razryva khimicheskikh svyazey. Potentsialy ionizatsii i srodstvo k elektronu. – M.: Nauka, 1974. – 351 s.
13. Temperaturnye zavisimosti privedennoy energii Gibbsa nekotorykh neorganicheskikh veshchestv / G.K. Moiseev, N.A. Vatolin, L.A. Marshuk, N.I. Il'inykh. – Ekaterinburg: Izd-vo UrO RAN, 1997. – 230 s.