«Environmental protection in oil and gas complex»

New sorption material for oil and petroleum products spills recovery from water bodies surfaces

UDC: 661.18
DOI: 10.33285/2411-7013-2022-1(304)-22-28

Authors:

¹ Belgorod State Technological University named after V.G. Shukhov, Belgorod, Russian Federation

Keywords: oil and petroleum products, magnetically-operated carbon-containing sorption material, waste kieselguhr sludge, magnetite, thermal modification, carbon layer, hydrophobicity, oil-receptivity, oil capacity, floatability

Annotation:

A new magnetically-operated petroleum sorbent has been developed as a result of thermal treatment at the temperature of 450 ºС of a raw mixture, made up of kieselguhr sludge, generated in refined vegetable oil production technology, and of a ferromagnetic component – iron-ore concentrate, obtained at iron ore beneficiation, in the amount from 10 to 30%. It has been determined that magnetic properties of the resulting petroleum sorbents are preserved after thermal treatment, which is explained by partial oxidation of magnetite to maghemite (γ-Fe2O3), also having magnetic properties, at temperature 450°С. The main properties of the obtained magnetically-operated carbon-containing petroleum sorbents were studied – their oil capacity made up 3.05 g/g at magnetite content of 10 %. it has been demonstrated that the sorption materials with various magnetite content are characterized with hydrophobicity and oil-receptivity, which is explained by the presence of compound ethers or lacton, contained in vegetable waxes and wax-like substances of kieselguhr sludge, on the sorbents’ carbon surface. In their oil-saturated state the obtained petroleum sorbents are characterized with high floatability – staying on the water surface up to 120 hours, which provides sufficient time for oil spill response and gathering of oil-saturated sorption materials.

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