Scientific and technical journal

«Environmental protection in oil and gas complex»

ISSN 2411-7013

Environmental protection in oil and gas complex
Components of petrochemical products in the environment

UDC: 504.054
DOI: 10.33285/2411-7013-2022-6(309)-23-29

Authors:

MAZLOVA ELENA A.1,
ZAPOROZHSKAYA ANASTASIYA A.1,
MOROZOVA ANASTASIYA S.1

1 National University of Oil and Gas "Gubkin University", Moscow, Russia

Keywords: petrochemical products, plastic waste, microplastics, phthalates, water pollution

Annotation:

Petrochemical products are diverse and include derivatives of both organic chemistry processes of hydrocarbons and synthesis processes – rubbers and polymers. The study of polymer products behavior in the environment is of scientific interest due to the global problem of plastic waste accumulation as a result of anthropogenic activities. Some plastic additives, when degraded, enter the environment, are included in the trophic chains and have a toxic effect on living organisms. The main share of modifying additives is occupied by plasticizers, and among them the most common and toxic for living organisms are additives from salts and esters of phthalic (orthophthalic) acid. The article considers a group of phthalates: dimethyl phthalate (DMPhL), dibutyl phthalate (DBPhL), diethyl phthalate (DEPhL), butylbenzyl phthalate (BBPhL), dioctyl phthalate (DOPhL), bis (2-ethylhexyl) phthalate (BPhL). The results of the qualitative and quantitative analysis of the rivers in Moscow and Moscow region, comparative assessment of the state of objects under study contaminate by phthalates, potential risk assessment and biotesting of samples with the highest concentration of toxic phthalate additives are presented.

Bibliography:

1. Issledovanie mikroplastika v pribrezhnoy zone rossiyskikh morey i rek / A.S. Morozova, E.A. Mazlova, Ya.Yu. Blinovskaya [i dr.] // Nauka, obrazovanie, proizvodstvo v reshenii ekologicheskikh problem (Ekologiya-2020): materialy XVI Mezhdunar. nauch.-tekhn. konf., posvyashchennoy 75-letiyu Pobedy v Velikoy Otechestvennoy voyne: v 2 t. – Ufa: Ufimskiy gos. aviats. tekhn. un-t, 2020. – T. 2. – S. 187–198.
2. Blinovskaya Ya.Yu., Yakimenko A.L. Analiz zagryazneniya akvatorii zaliva Petra Velikogo (Yaponskogo morya) mikroplastikom // Uspekhi sovremennogo estestvoznaniya. – 2018. – № 1. – S. 68–73.
3. Courtney A., Baker J., Bamford H. Proceedings of the International Research Workshop on the Occurrence, Effects and Fate of Microplastic Marine Debris, Sept. 9–11, 2008. – NOAA Technical Memorandum NOS-OR&R-30. – 2009.
4. Barshteyn R.S., Kirilovich V.I., Nosovskiy Yu.E. Plastifikatory dlya polimerov. – M.: Khimiya, 1982. – 200 s.
5. Toksichnost' i opasnost' ftalatov (analiz literaturnykh svedeniy) / I.E. Shkaeva, S.A. Solntseva, O.S. Nikulina [i dr.] // Toksikologicheskiy vestn. – 2019. – № 6(159). – S. 3–9. – DOI: 10.36946/0869-7922-2019-6-3-9
6. Golubchikov S.N. Malye reki kak indikator prirodopol'zovaniya // Energiya: ekonomika, tekhnika, ekologiya. – 2005. – № 1. – S. 56–60.
7. GOST 17.1.5.05-1985. Okhrana prirody. Gidrosfera. Obshchie trebovaniya k otboru prob poverkhnostnykh i morskikh vod, l'da i atmosfernykh osadkov. – Vved. 1986–07–01. – M.: Izd-vo standartov, 2001. – 12 s.
8. GOST 17.1.5.01-1980. Okhrana prirody. Gidrosfera. Obshchie trebovaniya k otboru prob donnykh otlozheniy vodnykh ob"ektov dlya analiza na zagryaznennost'. – Vved. 1982–01–01. – M.: Izd-vo standartov, 2002. – 7 s.
9. NDP 30.1:2:3.68-2009. Metodika izmereniy massovykh kontsentratsiy organicheskikh soedineniy v pit'evykh, prirodnykh i stochnykh vodakh metodom khromato-mass-spektrometrii. – M.: ROSA, 2011. – 33 s.
10. Ftalaty v donnykh otlozheniyakh Kaspiyskogo morya / V.O. Tatarnikov, A.N. Korshenko, A.I. Kochetkov, D.Kh. Azmukhambetova // Tr. Gos. okeanograficheskogo in-ta. – 2020. – № 221. – S. 143–153.
11. Occurrence, toxicity and risk assessment of plastic additives in Besos river, Spain / G. Bolívar-Subirats, C. Rivetti, M. Cortina-Puig [et al.] // Chemosphere. – 2020. – Vol. 263. – DOI: 10.1016/j.chemosphere.2020.128022
12. PND F T 14.1:2:3:4.12-06/T 16.1:2:2.2:2.3:3.9-06. Metodika izmereniy kolichestva Daphnia magna straus dlya opredeleniya ostroy toksichnosti pit'evykh, presnykh prirodnykh i stochnykh vod, vodnykh vytyazhek iz gruntov, pochv, osadkov stochnykh vod, donnykh otlozheniy, otkhodov proizvodstva i potrebleniya metodom pryamogo scheta. – M.: Feder. tsentr analiza i otsenki tekhnogennogo vozdeystviya, 2021. – 51 s.
13. Benzyl butyl phthalate / National Library of Medicine. National Center for Biotechnology Information. – 2022. – URL: https://pubchem.ncbi.nlm.nih.gov/compound/2347 (data obrashcheniya 15.04.2022).
14. Di-n-Octyl phthalate / National Library of Medicine. National Center for Biotechnology Information. – 2022. – URL: https://pubchem.ncbi.nlm.nih.gov/source/hsdb/1345 (data obrashcheniya 15.04.2022).