Research of the regularities of surface-active and ecotoxicological properties of oleic acid aminoamides
UDC: 504.06:677.042.23
DOI: 10.33285/2411-7013-2023-1(310)-5-12
Authors:
STARODUBTSEVA KSENIIA A.1,
ZAVOROTNY VITALIY L.
1,
GRECHISHCHEVA NATALIA YU.1
1 National University of Oil and Gas "Gubkin University", Moscow, Russia
Keywords: aminoamides of oleic acid, hydrophilic-lipophilic balance, biodegradability, octanol:water distribution coefficient, hydrophobic properties, emulsifying properties, oil-based drilling muds
Annotation:
The article studies the regularities of surface-active and ecotoxicological properties of oleic acid aminoamides. The results of the calculations of the hydrophilic-lipophilic balance, the octanol: water distribution coefficient the degree of biodegradability of the products of the interaction of oleic acid with polyethylene polyamines with the number of amino-groups from 2 to 4 are given. It has been shown that in the range of hydrophilic-lipophilic balance values from 3 to 6 (inverse emulsion emulsifiers), mono-substituted aminoamides of oleic acid based on diethylenetriamine are less toxic and more biodegradable. Hydrophobizing and emulsifying properties of the products of oleic acid amidation by diethylenetriamine are experimentally confirmed.
Bibliography:
1. Starodubtseva K.A., Kuznetsov A.E. Razrabotka reagentov-gidrofobizatorov dlya ERUO s nizkotoksichnymi i pozharobezopasnymi svoystvami // Neft' i gaz – 2018: sb. tr. 72-y Mezhdunar. molodezh. nauch. konf., Moskva, 23–26 apr. 2018 g. – M.: RGU nefti i gaza (NIU) im. I.M. Gubkina, 2018. – T. 2. – S. 430.
2. Perspektivy primeneniya otechestvennykh mineral'nykh masel v kachestve dispersionnoy sredy burovykh promyvochnykh zhidkostey / V.L. Zavorotnyy, A.V. Zavorotnyy, S.N. Shishkov [i dr.] // Neft'. Gaz. Novatsii. – 2016. – № 3. – S. 47–51.
3. Zavorotnyy V.L. Perspektivy primeneniya burovykh rastvorov na sinteticheskoy nevodnoy osnove (RNSO) // Neft'. Gaz. Novatsii. – 2018. – № 6. – S. 51–56.
4. Bocharov V.V., Raevskaya M.V. Termodinamika protsessov adsorbtsii PAV aktivnym ilom kak osnova dlya otbora biorazlagaemykh produktov // Bytovaya khimiya. – 2017. – № 65.
5. Bocharov V.V., Meshcheryakov S.V., Ryzhkova O.A. Prognozirovanie biorazlagaemosti PAV // Zashchita okruzhayushchey sredy v neftegazovom komplekse. – 2010. – № 1. – S. 28–31.
6. Zavorotnyy V.L., Smirnova T.S., Stain A.M. Otsenka i prognoz ekotoksikologicheskikh kharakteristik khimicheskikh reagentov i ikh smesey // Neftepromyslovaya khimiya: tez. dokl. VI Vseros. nauch.-prakt. konf. – M.: RGU nefti i gaza im. I.M. Gubkina, 2011. – S. 107–108.
7. Griffin W.C. Classification of surface-active Agents by "HLB" // J. of the Society of Cosmetic Chemists. – 1949. – Vol. 1. – P. 311–326.
8. Glushchenko V.N. Obratnye emul'sii i suspenzii v neftegazovoy promyshlennosti. – M.: Interkontakt Nauka, 2008. – 725 s.
9. Virtual Computational Chemistry Laboratory. – URL: http://www.vcclab.org/lab/alogps/ (data obrashcheniya 09.05.2021).
10. EPI Suite™ – Estimation Program Interface. – URL: https://www.epa.gov/tsca-screening-tools/epi-suitetm-estimation-program-interface (data obrashcheniya 09.05.2021).
11. Hydroxy- and Aminoethyl Imidazolines of Cottonseed Oil Fatty Acids as Additives for Diesel Fuels / V.M. Abbasov, T.A. Mammadova, K.R. Veliyev, Kh.H. Kasamanli // Open J. of Synthesis Theory and Applications. – 2015. – Vol. 4, No. 2. – P. 33–39. – DOI: 10.4236/ojsta.2015.42004
12. Abramzon A.A., Zaychenko L.P., Fayngol'd S.N. Poverkhnostno-aktivnye veshchestva. Sintez, analiz, svoystva, primenenie / pod red. A.A. Abramzona. – L.: Khimiya, 1988. – 200 s.
13. Ispol'zovanie parametra GLB dlya prognozirovaniya funktsiy poverkhnostno-aktivnykh veshchestv / V.L. Zavorotnyy, A.V. Zavorotnyy, M.M. Lyushin, K.A. Starodubtseva // Neftepromyslovaya khimiya: Materialy VI Mezhdunar. nauch.-prakt. konf. (XIV Vseros. nauch.-prakt. konf.), Moskva, 27 iyunya 2019 g. – M.: RGU nefti i gaza (NIU) im. I.M. Gubkina, 2019. – S. 81–84.
14. GOST 33697-2015 (ISO 10414-2:2011) Rastvory burovye na uglevodrodnoy osnove. Kontrol' parametrov v promyslovykh usloviyakh. – Vved. 2017–08–01. – M.: Standartinform, 2016. – V, 123 s. – URL: https://base.garant.ru/71680668/ (data obrashcheniya 09.05.2021).
15. Ob utverzhdenii Plana meropriyatiy po importozameshcheniyu v otrasli neftegazovogo mashinostroeniya Rossiyskoy Federatsii: Prikaz Minpromtorga Rossii ot 16.04.2019 № 1329. – URL: http://www.consultant.ru/document/cons_doc_LAW_322994/ (data obrashcheniya 09.05.2021).
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