«Environmental protection in oil and gas complex»

Resource-saving technology of petroleum raw material replacement by the product of vegetable oil deoxygenesis

UDC: 502.08
DOI: -

Authors:

¹ Bumatica, Perm, Russia
² Perm State National Research University, Perm, Russia
³ Perm National Research Polytechnic University, Perm, Russia

Keywords: renewable resources, biofuel, liquid fuel, dioxygenesis, calorific value, slow pyrolysis, motor transport, resource saving, vegetable oil, triglycerides

Annotation:

Transition to renewable energy sources for providing the concept of sustainable development is currently being proposed. This task of the oil and gas complex can be solved by replacement of hydrocarbons mineral sources by raw materials of plant origin, that are not only a renewable resource, but also reduces the environmental burden produced by the development of oil and gas fields. At present biofuels are usually considered as complex esters of simple alcohols obtained by transesterification of triglycerides of plant origin. It is shown that any biofuels based on complex esters have significant operational disadvantages arising from their chemical structure, which necessarily implies the presence of oxygen atoms in the molecule. The triglycerides transesterification replacement by deoxygenesis during processing of triglycerides for improving the operational characteristics of biofuels is proposed. It has been established that slow pyrolysis under pressure leads to reduction of oxygen-containing compounds in the composition of biofuels and to a corresponding increase of calorific value and a decrease of the product viscosity. The prospects for the proposed technical solution from the point of view of the sustainable development concept and the transition to a renewable feedstock for the oil and gas complex are discussed.

Bibliography:

1. Owen N.A., Inderwildi O.R., King D.A. The status of conventional world oil reserves – Hype or cause for concern? // Energy Policy. – 2010. – Vol. 38, Issue 8. – P. 4743–4749. – DOI: 10.1016/j.enpol.2010.02.026
2. Primenenie smazochnykh materialov na osnove rastitel'nykh masel / R.R. Araslanov, I.R. Tatur, V.G. Spirkin, A.S. Bogdanova // Zashchita okruzhayushchey sredy v neftegazovom komplekse. – 2021. – № 3(300). – S. 32–37. – DOI: 10.33285/2411-7013-2021-3(300)-32-37
3. Nigam P.S., Singh A. Production of liquid biofuels from renewable resources // Progress in Energy and Combustion Science. – 2011. – Vol. 37, Issue 1. – P. 52–68. – DOI: 10.1016/j.pecs.2010.01.003
4. El-Hamidi M., Zaher F.A. Production of vegetable oils in the world and in Egypt: an overview // Bulletin of the National Research Centre. – 2018. – Vol. 42. – Article No. 19 (2018). – DOI: 10.1186/s42269-018-0019-0
5. Circular Bioeconomy in Action: Collection and Recycling of Domestic Used Cooking Oil through a Social, Reverse Logistics System / M.I. Loizides, X.I. Loizidou, D.L. Orthodoxou, D. Petsa // Recycling. – 2019. – Vol. 4, Issue 2. – P. 16. – DOI: 10.3390/recycling4020016
6. Developments in in-situ (trans) esterification for biodiesel production: A critical review / Alchris Woo Go, S. Sutanto, Lu Ki Ong [et al.] // Renewable and Sustainable Energy Reviews. – 2016. – Vol. 60. – P. 284–305. – DOI: 10.1016/j.rser.2016.01.070
7. Yazykov N.A., Simonov A.D., Yakovlev V.A. Raschetnyy metod otsenki nizshey teploty sgoraniya tverdykh topliv na osnove dannykh tekhnicheskogo analiza // Zhurn. SFU. Ser.: Khimiya. – 2018. – T. 11, № 1. – S. 93–109. – DOI: 10.17516/1998-2836-0061
8. Markov V.A., Chaynov N.D., Loboda S.S. Fiziko-khimicheskie svoystva neftyanykh motornykh topliv s dobavkami rastitel'nykh masel i ikh vliyanie na pokazateli dizelya // Vestn. MGTU im. N.E. Baumana. Ser. Mashinostroenie. – 2018. – № 5(122). – S. 108–122. – DOI: 10.18698/0236-3941-2018-5-108-122
9. Markov V.A., Chaynov N.D., Loboda S.S. Fiziko-khimicheskie svoystva smesevykh dizel'nykh biotopliv s dobavkami rastitel'nykh masel i ikh vosplamenyaemost' // Vestn. MGTU im. N.E. Baumana. Ser. Estestvennye nauki. – 2018. – № 4(79). – S. 115–128. – DOI: 10.18698/1812-3368-2018-4-115-128
10. Issledovanie vliyaniya perekhoda avtomobil'nogo transporta na ekologicheskiy standart "Evro-5" na vozdushnyy basseyn goroda / N.N. Vershinin, A.D. Shumilin, A.V. Volkova, L.A. Avdonina // Nadezhnost' i kachestvo slozhnykh sistem. – 2017. – № 2(18). – S. 83–89. – DOI: 10.21685/2307-4205-2017-2-12
11. Proizvodstvo uglevodorodnykh topliv na osnove al'ternativnogo neneftyanogo syr'ya / V.F. Tret'yakov, A.M. Ilolov, A.D. Budnyak [i dr.] // Neftegazokhimiya. – 2017. – № 3. – S. 35–40.
12. Choudhary T.V., Phillips C.B. Renewable fuels via catalytic hydrodeoxygenation // Applied Catalysis A: General. – 2011. – Vol. 397, Issue 1-2. – P. 1–12. – DOI: 10.1016/j.apcata.2011.02.025
13. Advanced green approaches for the synthesis of NiCu-containing catalysts for the hydrodeoxygenation of anisole / N.S. Nesterov, A.A. Smirnov, V.P. Pakharukova [et al.] // Catalysis Today. – 2021. – Vol. 379. – P. 262–271. – DOI: 10.1016/j.cattod.2020.09.006
14. Recent advances in one-stage conversion of lipid-based biomass-derived oils into fuel components – aromatics and isomerized alkanes / P.M. Yeletsky, R.G. Kukushkin, V.A. Yakovlev, B.H. Chen // Fuel. – 2020. – Vol. 278. – P. 118255. – DOI: 10.1016/j.fuel.2020.118255
15. Sintez beskislorodnogo zhidkogo topliva medlennym pirolizom rastitel'nogo syr'ya pod davleniem / S.Yu. Chudinov, M.P. Krasnovskikh, N.N. Slyusar' [ i dr.] // Ekologiya i prom-st' Rossii. – 2023. – T. 27, № 3. – S. 28–32. – DOI: 10.18412/1816-0395-2023-3-28-32
16. Akkaya M.R. Prediction of fatty acid composition of sunflower seeds by near-infrared reflectance spectroscopy // J. of Food Science and Technology. – 2018. – Vol. 55, Issue 6. – P. 2318–2325. – DOI: 10.1007/s13197-018-3150-x
17. Heterogeneous sulfur-free hydrodeoxygenation catalysts for selectively upgrading the renewable bio-oils to second generation biofuels / Xin Li, Xingyi Luo, Yangbin Jin [et al.] // Renewable and Sustainable Energy Reviews. – 2018. – Vol. 82, Part 3. – P. 3762–3797. – DOI: 10.1016/j.rser.2017.10.091