Assessment of corrosion inhibitors efficiency at gas production and processing facilities
UDC: 628.5:504.054
DOI: -
Authors:
VAGAPOV R.K.
1,
GAIZULLIN A.D.1
1 Gazprom VNIIGAZ, Moscow region, Russia
Keywords: gas field, waste water, inhibitory protection, influence on the human body, emulsion formation, methods of emulsion destruction, film-forming properties of inhibitors
Annotation:
The authors of the article present a comprehensive approach to the study of corrosion inhibitor properties and requirements for them at gas fields. It is noted that inhibitory reagents should be harmless to human health, have a high protective potential against internal corrosion and produce no negative impact on technological processes during the preparation and processing of gas and gas condensate. On the one hand, corrosion inhibitors ensure the reliable operation of equipment and gas pipelines, preventing possible emergency emissions of hydrocarbons into the air, water and soil and the associated environmental consequences. On the other hand, insufficient separation of the hydrocarbon phase from the aqueous medium at elevated concentrations of inhibitors, leading to emulsion formation, can cause problems when purifying wastewaters before injecting them into the reservoir thus and contaminating groundwater by hydrocarbons. The conditions for emulsions formation during hydrocarbon processing at gas fields are considered. The efficiency of thermal and chemical emulsion destruction methods is studied. The protective properties of corrosion inhibitors films are assessed using the polarization resistance method.
Bibliography:
1. Vagapov R.K. Stoykost' staley v ekspluatatsionnykh usloviyakh gazovykh mestorozhdeniy, soderzhashchikh v dobyvaemykh sredakh agressivnyy CO2 // Materialovedenie. – 2021. – № 8. – S. 41–47. – DOI: 10.31044/1684-579X-2021-0-8-41-47
2. Gossen L.P., Velichkina L.M. Ekologicheskie problemy neftegazovogo kompleksa (obzor) // Neftekhimiya. – 2006. – T. 26, № 2. – S. 83–88.
3. Inhibiting formulations against hydrogen sulfide corrosion of carbon steel / L.E. Tsygankova, A.A. Uryadnikov, A.E. Abramov, T.V. Semenyuk // Int. J. of Corrosion and Scale Inhibition. – 2022. – Vol. 11, No. 1. – P. 102–110. – DOI: 10.17675/2305-6894-2021-11-1-5
4. Nauchnyy analiz tekhnicheskogo sostoyaniya i zashchity skvazhinnogo oborudovaniya i promyslovykh truboprovodov PAO "Gazprom" v usloviyakh dobychi i transportirovki korrozionno-agressivnogo gaza. Chast' 1 / P.P. Slugin, I.R. Yagafarov, R.R. Kantyukov [i dr.] // Gazovaya prom-st'. – 2023. – № 9(854). – S. 64–71.
5. Nabutovskiy Z.A., Antonov V.G., Filippov A.G. Problemy korrozii i ingibitornoy zashchity na mestorozhdeniyakh prirodnogo gaza // Praktika protivokorrozionnoy zashchity. – 2000. – № 3(17). – S. 50–56.
6. Slugin P.P., Polyanskiy A.V., Ermilov O.M. Sposob povysheniya izvlecheniya kondensata na Bovanenkovskom NGKM // Nauka i tekhnika v gazovoy prom-sti. – 2018. – № 1(73). – S. 33–37.
7. Opyt modernizatsii tekhnologicheskogo oborudovaniya podgotovki gaza achimovskoy tolshchi Urengoyskogo neftegazokondensatnogo mestorozhdeniya / A.Yu. Koryakin, V.F. Kobychev, V.V. Aleksandrov [i dr.] // Gazovaya prom-st'. – 2019. – № S1(782). – S. 64–70.
8. Ekologicheskie problemy utilizatsii stochnykh vod pri ekspluatatsii gazovykh mestorozhdeniy / N.I. Vasil'ev, P.G. Talalay, G.P. Talalay, N.A. Tsvetkov // Zap. Gornogo in-ta. – 2010. – T. 187. – S. 36–39.
9. Modernizatsiya sistemy podgotovki promyshlennykh stochnykh vod na primere gazokondensatnogo promysla № 5 Urengoyskogo NGKM / R.R. Yalaletdinov, S.D. Khusaenov, D.A. Ivanov [i dr.] // Zashchita okruzhayushchey sredy v neftegazovom komplekse. – 2024. – № 1(316). – S. 13–18.
10. STO Gazprom 9.3-007-2010. Zashchita ot korrozii. Metodika laboratornykh ispytaniy ingibitorov korrozii dlya oborudovaniya dobychi, transportirovki i pererabotki korrozionno-aktivnogo gaza. – Vved. 2011–07–11. – M.: Gazprom, 2011. – VII, 91 s.
11. Murav'eva S.A., Mel'nikov V.G. Vliyanie stroeniya azotsoderzhashchikh soedineniy na ikh penogasyashchuyu i deemul'giruyushchuyu sposobnost' // Teoreticheskie osnovy khim. tekhnologii. – 2005. – T. 39, № 1. – S. 83–87.
12. O nekotorykh zakonomernostyakh po podboru effektivnykh deemul'gatorov dlya podgotovki nefti na promyslakh / A.V. Grishagin, V.N. Kozhin, D.V. Kashaev, O.V. Gladunov // Neftepromyslovoe delo. – 2024. – № 3(663). – S. 43–48.
13. Kantyukov R.R., Zapevalov D.N., Vagapov R.K. Issledovanie korrozionnoy aktivnosti sred i stoykosti ispol'zuemykh materialov v usloviyakh prisutstviya agressivnogo dioksida ugleroda // Izv. vuzov. Chernaya metallurgiya. – 2021. – T. 64, № 11. – S. 793–801. – DOI: 10.17073/0368-0797-2021-11-793-801
14. Pitting corrosion failure analysis of a wet gas pipeline / H. Mansoori, R. Mirzaee, F. Esmaeilzadeh [et al.] // Engineering Failure Analysis. – 2017. – Vol. 82. – P. 16–25. – DOI: 10.1016/j.engfailanal.2017.08.012
15. Vagapov R.K., Zapevalov D.N. Vozmozhnosti ispol'zovaniya i vybor tekhnologii ingibitornoy zashchity ot korrozii ob"ektov dobychi gaza, kharakterizuyushchikhsya prisutstviem dioksida ugleroda // Nauka i tekhnika v gazovoy prom-sti. – 2020. – № 1(81). – S. 72–79.
16. Film former corrosion inhibitors for oil and gas pipelines – A technical review / M. Askari, M. Aliofkhazraei, S. Ghaffari, A. Hajizadeh // J. of Natural Gas Science and Engineering. – 2018. – Vol. 58. – P. 92–114. – DOI: 10.1016/j.jngse.2018.07.025