«Proceedings of Gubkin University»

EXPANSION OF RESOURCE BASE OF DIAMOND-LIKE STRUCTURE

UDC: 547
DOI: -

Authors:

¹ Gubkin Russian State University of Oil and Gas

Keywords: diamondoids, protodiamondoids, adamantanes, diamantanes, triamantanes, tetramantanes

Annotation:

Diamond-like structure hydrocarbons due to their physical and chemical properties features find a wide range of applications in various fields of science, technology and industry: nanotechnology, medicine, manufacturing of highly resistant polymer materials and others. However, the existing methods for the synthesis of diamondoids are complex and multistage, and require further improvement. We performed thermolysis of asphaltenes, resins and high-molecular saturated (boiling above 350 °C) petroleum fractions of different genotypes, catalytic transformations of paraffin-cycloparaffinic fractions (boiling within 180-350 °C above 350 °C) of oils, catalytic thermal transformations of oxygen-containing compo-unds - precursors of petroleum hydrocarbons, thermo-lysis of macromolecular n-alkanes, as well as catalytic transformations of bio-mass of bacteria. Analysis of the hydrocarbon composition of the original oils, paraffin-cycloparaffinic fractions, thermolysis products and catalytic transforma-tions was carried out by capillary gas-liquid chromatography and chromato-graphy-mass spectrometry. We have found that diamond-like structure hydro-carbons C₁₀₂₃ form as a result of the above transformations. Thus a possibility of obtaining hydrocarbon of adamantane series from alternative sources was shown.

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