«Труды Российского государственного университета нефти и газа имени И.М. Губкина»

ФУНДАМЕНТАЛЬНЫЕ УРАВНЕНИЯ СОСТОЯНИЯ Н-ДОДЕКАНА И Н-ТРИДЕКАНА

УДК: 536.7
DOI: -

Авторы:

¹ РГУ нефти и газа имени И.М. Губкина
² Калининградский государственный технический университет

Ключевые слова: температура, давление, плотность, теплоемкость, энтальпия, энтропия, уравнение состояния

Аннотация:

Разработаны фундаментальные 14-константные уравнения состояния универсальной формы, описывающие с высокой точностью все термо-динамические свойства н-додекана и н-тридекана в диапазоне температуры от тройной точки до ~700 К при давлениях до 100 МПа. Средняя погрешность описания плотности жидкой фазы на линии насыщения составляет 0,1–0,3 %, газовой фазы на линии насыщения – 0,3–1,5 %, давления насыщенного пара – 0,2–1,0 %, плотности жидкой фазы при повышенных давлениях 0,1–0,4 %, изобарной теплоемкости жидкой фазы – 0,4–0,8 %, скорости звука 0,5–1,0 %. Для н-тридекана фундаментальное уравнение получено впервые.

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